Radius of Gyration Below 10 nm

Related Literature - LenS3 Detector

System & Columns

EcoSEC GPC System with RI detector

LenS3 Multi-Angle Light Scattering detector

1 × TSKgel GMHHR-H (7.8 mm ID × 30 cm)

LALS (red), RALS (blue) and HALS (green) signals with baselines and integration limits for PS 40K standard

Measured values of radius of gyration, R_g,z, of PS standards
Sample	Mw	Rg,z	Literature values*
PS 100K	100,400	12.0	13.2
PS 40K	40,800	7.6	8.1
PS 30K	30,100	6.6	6.8
PS 20K	18,600	5.5	5.3
PS 10K	10,700	4.6	3.9
* Literature values calculated using the correlation R_g = 0.0245•MW^0.546

System & Conditions

Polystyrene (PS) standards below 100K

THF at 1.0 mL/min; T = 35 °C (pumps, column and RI)

Concentration = 1 - 3 mg/mL; injection volume = 50 µL